Raw data for "Unlocking the Potential of Organoaluminum Reagents for Versatile C–C Couplings Using YPhos-Pd Catalysts"

Unlike other earth-abundant organometallic reagents, the protocol demonstrates broad functional group tolerance, even allowing for late-stage functionalizations of complex molecules.

In general, high selectivities and yields are achieved, while maintain-ing the high reactivity characteristics of this class of compounds even at room temperature. The presented protocol high-lights the key advantages of this thus far underestimated class of nucleophiles in coupling chemistry and illustrates both the strengths and limitations of in situ generated alkyl-, aryl-, alkenyl-, and alkynylaluminum reagents. DATASET DESCRIPTION: Single folders were created for all experiment types (NMR, IR, HRMS, GC-MS) for isolated compounds.