Data · dataset · 2026
Deboronative Asymmetric Suzuki–Miyaura Cross-Coupling of Alkylboronic Esters Enabled by Dual Photoredox and Nickel Catalysis
Listed in ZivaHub
The transition-metal-catalyzed asymmetric Suzuki–Miyaura cross-coupling of alkylboron reagents remains highly challenging, especially with racemic alkylboronic esters.
Description
Herein, we disclose the first enantioconvergent deboronative Suzuki–Miyaura cross-coupling of racemic alkylboronic esters with (hetero)aryl halides enabled by dual photoredox and nickel catalysis. The protocol displays broad scope across (hetero)aryl bromides bearing functionally diverse substituents.
The cooperative use of 4-cyanopyridine and pentafluoropyridine is crucial for achieving both high reactivity and excellent enantioselectivity.
Links
Where it is published
- DOI doi.org/10.1021/acs.orglett.6c03250.s001 ↗
DOI / persistent id · from zivahub uct ac za
Catalogue records · 1
- OAI-PMH record api.figshare.com/v2/oai?verb=GetRecord&metadataPrefix=oai_dc&identifier=oai%3Af… ↗
metadata API · from zivahub uct ac za
Topics
- From keywords
- Chemistry · Earth & Environmental Science · Immunology · Life Sciences · Medicine & Health
Provenance · 1 source records, 10 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| ZivaHub | oai:figshare.com:article/34028421 | 12 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| access_level | source · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | |
| concepts[field].anzsrc:group:3204 | mapping · zivahub uct ac za | vocabulary-mapper@1.0.0 | keywords['Immunology'] |
| concepts[field].local:field:chemistry | mapping · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | |
| concepts[field].local:field:earth-environmental | mapping · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | |
| concepts[field].local:field:life-sciences | mapping · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | |
| concepts[field].local:field:medicine-health | mapping · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | |
| description | source · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | /metadata/dc/description |
| license | source · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | /metadata/dc/rights |
| publication_date | source · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | |
| title | source · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | /metadata/dc/title |