Synthesis and structure of lateral halogenated V-shaped liquid crystal molecules based on a 1,7-naphthalene central core and alkylthio tails

A series of small angle bent-core (V-shaped) mesogens carrying 1,7-naphthalene as a central core linked with lateral halogenated (chlorinated or fluorinated) Schiff-base side wings and alkylthio terminal tails of variable carbon number ( n = 12, 16) was synthesised in order to reduce the transition temperature and improve the phase stability of bent-core liquid crystal molecules. Differential scanning calorimetry (DSC), polarising optical microscopy (POM), small-angle X-ray scattering system (SAXS) and two-dimensional X-ray diffractometer were applied to ascertain the mesomorphic structure and phase transition temperatures of the compounds.

The results confirm that all the molecules show thermotropic liquid crystalline behaviour and exhibit hexagonal columnar phase (Col h ) in a certain temperature range. Compared with the homologous compounds without lateral halogen, the cleaning point temperature of lateral halogenated V-shaped compounds generally decrease and the Col h phase ranges are more extensive. The influence of lateral chlorine on the cleaning point temperature is more obvious, as well as the effect of lateral fluorine on the range of Col h phase.