Data · dataset · 2024
Colour Tunability of Heteroleptic Ir(III) Complexes Through Second-Sphere Coordination
Listed in UNB Libraries Dataverse Research Data Repository
Raw data for: Novel H-bond-rich iridium (III) complexes with different systems of cyclometalating ligands bearing the general formula [Ir(C^N)2(N^N)] were synthesized, characterized and their photophysical properties measured.
Description
The incorporated guanidine moieties allow us to introduce a hydrogen-bonding array for the formation of self-assembled iridium hydrogen-bonded systems. Through a series of UV-Vis binding studies we demonstrated the host-guest chemistry of these systems display high levels of colour tuneability.
These hydrogen-bond interactions were also shown to have significant impacts on chromaticity, quantum yields and lifetimes with emphasis on energy transfer studies based on this second-sphere coordination approach. KEYWORDS: H-Bonding, Colour tuning, Second-Sphere Interactions
Links
Where it is published
- Dataverse dataset page dataverse.lib.unb.ca/dataset.xhtml?persistentId=doi%3A10.25545%2FAIBVAX ↗
landing page · from dataverse lib unb ca
- DOI doi.org/10.25545/aibvax ↗
DOI / persistent id · from dataverse lib unb ca
Catalogue records · 1
- Dataverse API dataverse.lib.unb.ca/api/datasets/:persistentId/?persistentId=doi%3A10.25545%2FAIBV… ↗
metadata API · from dataverse lib unb ca
Topics
- Stated by source
- Chemistry
- From keywords
- Chemistry
- Inferred from text
- Macromolecular and materials chemistry 73%
Provenance · 1 source records, 9 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| UNB Libraries Dataverse Research Data Repository | doi:10.25545/AIBVAX | 10 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| concepts[field].anzsrc:group:3403 | enrichment · dataverse lib unb ca | taxonomy-embedding@1.1.0 | title+keywords+description (73%) |
| concepts[field].dataverse_subject:chemistry | source · dataverse lib unb ca | connector:dataverse_lib_unb_ca@1.0.0 | /subjects |
| concepts[field].local:field:chemistry | mapping · dataverse lib unb ca | connector:dataverse_lib_unb_ca@1.0.0 | /subjects |
| created_date | source · dataverse lib unb ca | connector:dataverse_lib_unb_ca@1.0.0 | |
| description | source · dataverse lib unb ca | connector:dataverse_lib_unb_ca@1.0.0 | /description |
| publication_date | source · dataverse lib unb ca | connector:dataverse_lib_unb_ca@1.0.0 | |
| title | source · dataverse lib unb ca | connector:dataverse_lib_unb_ca@1.0.0 | /name |
| updated_date | source · dataverse lib unb ca | connector:dataverse_lib_unb_ca@1.0.0 | |
| version_label | source · dataverse lib unb ca | connector:dataverse_lib_unb_ca@1.0.0 |