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ICARUS Chamber Experiment: Hildebrandt Ruiz Lab_20171125_DECANE/nitric oxide/nitrite_Chlorine radical_Ammonium sulfate_dry

Listed in National Center for Atmospheric Research

Goals: Find SOA yield for decane + Cl under high NOx condition (NO and NO2 injected) and low RH.

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Investigate volatility behavior based on 2D thermograms.

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Ammonium sulfate seed (0.01M, 150 mL) was injected using an aerosol generation system. Cl2 gas, NO and NO2 gas were injected from their cylinders. 81 ug/m^3 of decane was injected into a glass bulb and heated clean air was made to flow over it, carrying the volatilized decane into the chamber. After ~30 minutes (sufficient mixing time), lights were turned on for 1 hour (13:49:37-14:49:31). 64.7 ug/m^3 of SOA was formed, giving a mass yield of 0.80.

This is Experiment #7 in associated publication. Organization: Hildebrandt Ruiz Lab Lab Affiliation: University of Texas at Austin, Austin, TX, USA Chamber: LHR Chamber Experiment Category: Gas phase chemical reaction, Volatility and partitioning, Aerosol formation Oxidant: Chlorine radical Reactants: DECANE, nitric oxide, nitrite Reaction Type: Photooxidation Temperature: 25 Seed Name: Ammonium sulfate

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