Data · dataset · 2026
Dicationic palladium(II) complexes as catalysts for alkene oxidation and isomerisation
Listed in ZivaHub and Deakin Research Online and DMU Figshare — shown once because both records carry DOI 10.17034/32641185.v1
Oxidations are fundamental reactions in chemistry for adding functionalities to various molecules, in particular the oxidation of alkenes to their corresponding carbonyls plays a key role in organic synthesis.
Description
Sustainable processes using molecular oxygen, hydrogen peroxide or tert-butyl hydroperoxide (TBHP) as the terminal oxidant are of interest as they are environmentally friendly and minimise the amount and toxicity of waste produced.
The ability to carry out these transformations efficiently has the potential for widespread application.<br><br>Within this thesis both the use of molecular oxygen and TBHP for the oxidation of terminal alkenes to methyl ketones using cationic palladium(II) catalysts will be studied. The aim is to optimise and improve current methods in the hope that more sustainable systems will be developed for further use on an industrial scale.
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In addition to this palladium(II) catalysts will also be used to convert terminal alkenes into their more desirable isomers.<br><br><i>Thesis is embargoed until 31 July 2030.</i>
Links
Where it is published
- DOI doi.org/10.17034/32641185.v1 ↗
DOI / persistent id · from zivahub uct ac za
Catalogue records · 1
- OAI-PMH record api.figshare.com/v2/oai?verb=GetRecord&metadataPrefix=oai_dc&identifier=oai%3Af… ↗
metadata API · from zivahub uct ac za
Topics
Provenance · 3 source records, 8 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| ZivaHub | oai:figshare.com:article/32641185 | 12 d ago | JSON v1 |
| Deakin Research Online | oai:figshare.com:article/32641185 | 12 d ago | JSON v1 |
| DMU Figshare | oai:figshare.com:article/32641185 | 12 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| access_level | source · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | |
| concepts[field].local:field:earth-environmental | mapping · figshare dmu ac uk | connector:figshare_dmu_ac_uk@1.0.0 | |
| concepts[field].local:field:earth-environmental | mapping · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | |
| concepts[field].local:field:earth-environmental | mapping · dro deakin edu au | connector:dro_deakin_edu_au@1.0.0 | |
| description | source · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | /metadata/dc/description |
| license_text | source · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | |
| publication_date | source · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | |
| title | source · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | /metadata/dc/title |