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Data · collection · 2016

Solid Phase Extraction and Removal of 2,4-dichlorophenol from Aqueous Samples using Magnetic Graphene Nanocomposite

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A Magnetic-graphene nanocomposite (Fe 3 O 4 -GNC) was prepared and used for the solid phase extraction and removal of 2,4-dichlorophenol from aqueous solutions.

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The physico-chemical properties were investigated using SEM, EDX, FTIR and TGA. Different factors affecting sorption capacity were studied systematically.

Results for kinetics studies revealed that 2,4-dichlorophenol sorption followed pseudo-second order kinetics and the qe value (987.45 mg/g) was in close agreement with experimental value (1000 mg/g). Thermodynamic study showed that the sorption is endothermic (∆Hº = +56.116 kJ mol −1 ) and spontaneous. The desorption studies were carried out for the reusability and extraction of 2,4-dichlorophenol from aqueous samples and 94% recoveries were obtained.

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The method was found feasible for the removal and preconcentration of trace analysis of 2,4-dichlorophenol in environmental water samples.

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DataCite10.6084/m9.figshare.c.2860369.v115 d agoJSON v1
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