Data · dataset · 2026
Rapid Aryne-Mediated Aryl Functionalization via Mechanically Assisted Microscale Mixing
Listed in TU Wien Research Data
We demonstrate that arynes can be generated and trapped efficiently through mechanically assisted microscale mixing on a standard vortex mixer.
Description
Brief vortex agitation enables ultra-fast generation and interception of these highly reactive intermediates with N-, O-, S-, and C-nucleophiles within 1 minute, therefore providing a low-energy-solvent minimized approach for aryl functionalization without the need for inert atmosphere, heating, or bulk solvent.Uploaded files: ZIP-folder: NMR data files for all compounds of this project.
These can be opened with all standard NMR-evaluation software (e.g. MestreNova, TopSpin, ACD-Labs, etc.) ZIP-folder: HRMS data files for all newly synthesized compounds of this project. These can be opened with all standard HRMS-evaluation software (e.g. Masshunter) .pdf document with a conversion table of the publication numbers of compounds into the number from the measured files .pdf document with the supporting info for the publication
Links
Where it is published
- TU Wien Research Data record researchdata.tuwien.ac.at/records/mhzc1-73q33 ↗
landing page · from researchdata tuwien ac at
- DOI doi.org/10.48436/mhzc1-73q33 ↗
DOI / persistent id · from researchdata tuwien ac at
Catalogue records · 1
- InvenioRDM API researchdata.tuwien.ac.at/api/records/mhzc1-73q33 ↗
metadata API · from researchdata tuwien ac at
Topics
- Stated by source
- aryne · micro mixing · nucleophile · organic chemistry · solvent-free · vortex mixer
- From keywords
- Chemistry · Organic chemistry
- Inferred from text
- Tabular 65%
Provenance · 1 source records, 15 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| TU Wien Research Data | mhzc1-73q33 | 11 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| access_level | source · researchdata tuwien ac at | connector:researchdata_tuwien_ac_at@1.0.0 | |
| concepts[field].anzsrc:group:3405 | mapping · researchdata tuwien ac at | vocabulary-mapper@1.0.0 | keywords['organic chemistry'] |
| concepts[field].local:field:chemistry | mapping · researchdata tuwien ac at | connector:researchdata_tuwien_ac_at@1.0.0 | |
| concepts[modality].local:modality:tabular | enrichment · researchdata tuwien ac at | keyword-concept-rules@1.0.0 | title+description (65%) |
| concepts[topic].invenio_subject:researchdata_tuwien_ac_at:aryne | source · researchdata tuwien ac at | connector:researchdata_tuwien_ac_at@1.0.0 | |
| concepts[topic].invenio_subject:researchdata_tuwien_ac_at:micro-mixing | source · researchdata tuwien ac at | connector:researchdata_tuwien_ac_at@1.0.0 | |
| concepts[topic].invenio_subject:researchdata_tuwien_ac_at:nucleophile | source · researchdata tuwien ac at | connector:researchdata_tuwien_ac_at@1.0.0 | |
| concepts[topic].invenio_subject:researchdata_tuwien_ac_at:organic-chemistry | source · researchdata tuwien ac at | connector:researchdata_tuwien_ac_at@1.0.0 | |
| concepts[topic].invenio_subject:researchdata_tuwien_ac_at:solvent-free | source · researchdata tuwien ac at | connector:researchdata_tuwien_ac_at@1.0.0 | |
| concepts[topic].invenio_subject:researchdata_tuwien_ac_at:vortex-mixer | source · researchdata tuwien ac at | connector:researchdata_tuwien_ac_at@1.0.0 | |
| description | source · researchdata tuwien ac at | connector:researchdata_tuwien_ac_at@1.0.0 | /metadata/description |
| license | source · researchdata tuwien ac at | connector:researchdata_tuwien_ac_at@1.0.0 | |
| publication_date | source · researchdata tuwien ac at | connector:researchdata_tuwien_ac_at@1.0.0 | |
| title | source · researchdata tuwien ac at | connector:researchdata_tuwien_ac_at@1.0.0 | /metadata/title |
| updated_date | source · researchdata tuwien ac at | connector:researchdata_tuwien_ac_at@1.0.0 |