Data · collection · 2016
Investigation of the structure and magnetism in lanthanide β-triketonate tetranuclear assemblies
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The preparation of discrete tetranuclear lanthanide/alkali metal (Ae) assemblies bearing a tribenzoylmethane ligand ( L H) is discussed.
Description
These assemblies have the general formula [Ln(Ae·HOEt)( L ) 4 ] 2 , where Ln 3+ = Gd 3+ , Tb 3+ , Dy 3+ , Ho 3+ and Ae + = Na + , K + , Rb + . The coordination geometries of the lanthanide species were analyzed and compared, revealing a trend between an eight-coordinate square antiprism and triangular dodecahedron dependent on the nature of lanthanide, alkali metal, and lattice solvent.
The potassium-containing analogs were also analyzed for their magnetic susceptibility.
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- Repository landing page figshare.com/collections/Investigation_of_the_structure_and_magnetism_in_la… ↗
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- DOI doi.org/10.6084/m9.figshare.c.3148093 ↗
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Topics
- Stated by source
- Biological sciences · Chemical sciences · Earth and related environmental sciences · Physical sciences
- From keywords
- Biochemistry and cell biology · Bioinformatics and computational biology · Cancer · Genetics · Medicine & Health
Provenance · 1 source records, 13 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| DataCite | 10.6084/m9.figshare.c.3148093 | 14 d ago | JSON v1 |
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