Data · collection · 2016
The first bismuth(II)–rhodium(II) oxypyridinate paddlewheel complexes: synthesis and structural characterization
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The first examples of heterobimetallic Bi–Rh bonded complexes supported by heteroatom ligands have been synthesized and structurally characterized.
Description
BiRh(hp) 4 ( 1 ) and BiRh(chp) 4 ( 2 ) each adopt a [4,0] O polar geometry with Bi–Rh bond distances of 2.5409(4) and 2.5848(1) Å, respectively (hp = 2-hydroxypyridine, chp = 6-chloro-2-hydroxypyridine). The relative oxophilicity of bismuth compared to rhodium clearly influences the selective formation of the [4,0] O arrangement, even for the sterically crowded 2 .
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- Repository landing page figshare.com/collections/The_first_bismuth_II_rhodium_II_oxypyridinate_padd… ↗
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- DOI doi.org/10.6084/m9.figshare.c.3142888 ↗
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- DataCite API api.datacite.org/dois/10.6084/m9.figshare.c.3142888 ↗
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Topics
- Stated by source
- Biological sciences · Chemical sciences · Clinical medicine · Computer and information sciences · Physical sciences
- From keywords
- Biochemistry and cell biology · Genetics · Immunology
Related
Provenance · 1 source records, 12 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| DataCite | 10.6084/m9.figshare.c.3142888 | 12 d ago | JSON v1 |
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|---|---|---|---|
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| concepts[field].fos:biological-sciences | source · DataCite | connector:datacite@1.0.0 | |
| concepts[field].fos:chemical-sciences | source · DataCite | connector:datacite@1.0.0 | |
| concepts[field].fos:clinical-medicine | source · DataCite | connector:datacite@1.0.0 | |
| concepts[field].fos:computer-and-information-sciences | source · DataCite | connector:datacite@1.0.0 | |
| concepts[field].fos:physical-sciences | source · DataCite | connector:datacite@1.0.0 | |
| created_date | source · DataCite | connector:datacite@1.0.0 | |
| description | source · DataCite | connector:datacite@1.0.0 | /data/attributes/descriptions |
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| publication_date | source · DataCite | connector:datacite@1.0.0 | /data/attributes/dates |
| title | source · DataCite | connector:datacite@1.0.0 | /data/attributes/titles/0/title |
| updated_date | source · DataCite | connector:datacite@1.0.0 |