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Structure · dataset · 2019

Evaluation of Fracture Toughness of Ultraviolet-Irradiated Polycarbonate Using the Essential Work of Fracture Method

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The essential work of fracture (EWF) method provides useful parameters to characterize the fracture toughness of polymers exposed to degrading environments under conditions associated with plane-stress state of failure.

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Exposure of polymeric engineering materials to ultraviolet (UV) radiation may produce macromolecular changes that impair their fracture toughness. In the present work, for the first time, the EWF method applying a double edge notched tensile specimen was used to quantify the fracture toughness behavior of polycarbonate (PC) exposed to different, 300 h and 600 h, UV irradiation times.

In addition, molar weight M ─ n determination, differential scanning calorimetry (DSC), Fourier transformed infrared spectroscopy (FTIR) and tensile tests were also investigated for non-irradiated and UV irradiated PC. The EWF results and scanning electron microscopy analysis revealed a significant reduction (39 % for 300h and 45 % for 600h of UV exposure) in fracture toughness associated with scission of the macromolecular chains.

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Other investigated properties, such as M ─ n, glass transition temperature, oxidation index and tensile strength, despite decreasing with UV exposure, did not show conclusive values.

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Automotive engineering 72% · Microscopy 75%

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DataCite10.6084/m9.figshare.767663012 d agoJSON v1
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