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Archive · collection · 2000

Chemical and isotopic compositions of samples from the Haakon Mosby mud volcano and nearby

Listed in PANGAEA

Authigenic carbonates in the caldera of an Arctic (72°N) submarine mud volcano with active methane-bearing fluid discharge are formed at the bottom surface during anaerobic microbial methane oxidation.

Description

The microbial community consists of specific methane-producing bacteria, which act as methanotrophic ones in conditions of excess methane, and sulfate reducers developing on hydrogen, which is an intermediate product of microbial CH4 oxidation.

Isotopically light carbon (aver. d13C = -28.9 per mil) of CO2 produced during CH4 oxidation is the main carbonate carbon source. Heavy oxygen isotope ratio (aver. d18O = 5 per mil) in carbonates is inherited from seawater sulfate. Rapid sulfate reduction (up to 12 mg S/dm**3/day) results in total exhausting of sulfate ion in the upper sediment layer (10 cm).

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Because of this carbonates can only be formed in surface sediments near the water-bottom interface. Salinity as well as CO3/Ca and Mg/Ca ratios correspond to the field of non-magnesian calcium carbonate precipitation. Calcite is the dominant carbonate mineral in the methane seep caldera, where it occurs in the paragenetic association with barite.

Radiocarbon age of carbonates is about 10 Ka.

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Catalogue records · 1

Topics

Inferred from text
Geochemistry 73%
Provenance · 1 source records, 8 field assertions
SourceKeyLast seenRaw
PANGAEAoai:pangaea.de:doi:10.1594/PANGAEA.78467112 d agoJSON v1
FieldAssertionExtractorEvidence
access_levelsource · PANGAEAconnector:pangaea@1.0.0
concepts[field].anzsrc:group:3703enrichment · PANGAEAtaxonomy-embedding@1.1.0title+keywords+description (73%)
concepts[field].local:field:earth-environmentalmapping · PANGAEAconnector:pangaea@1.0.0
descriptionsource · PANGAEAconnector:pangaea@1.0.0/metadata/dc/description
licensesource · PANGAEAconnector:pangaea@1.0.0/metadata/dc/rights
publication_datesource · PANGAEAconnector:pangaea@1.0.0
spatialsource · PANGAEAconnector:pangaea@1.0.0
titlesource · PANGAEAconnector:pangaea@1.0.0/metadata/dc/title