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Data · dataset · 2026

Airborne measurements of BrO and the sum of HOBr and Br2 over the Tropical West Pacific from 1 to 15 km during the CONvective TRansport of Active Species in the Tropics (CONTRAST) experiment

Listed in National Center for Atmospheric Research

A chemical ionization mass spectrometer was used to measure BrO and HOBr+Br-2 over the Tropical West Pacific Ocean within the altitude range of 1 to 15km, during the CONvective TRansport of Active Species in the Tropics (CONTRAST) campaign in 2014.

Description

Isolated episodes of elevated BrO (up to 6.6pptv) and/or HOBr+Br-2 (up to 7.3pptv) were observed in the tropical free troposphere (TFT) and were associated with biomass burning.

However, most of the time we did not observe significant BrO or HOBr+Br-2 in the TFT and the tropical tropopause layer (TTL) above our limits of detection (LOD). The 1min average LOD for BrO ranged from 0.6 to 1.6pptv and for HOBr+Br-2 ranged from 1.3 to 3.5pptv. During one flight, BrO observations from the TTL to the extratropical lowermost stratosphere were used to infer a profile of inorganic bromine (Br-y).

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Based on this profile, we estimated the product gas injection of bromine species into the stratosphere to be 2pptv. Analysis of Br-y partitioning further indicates that BrO levels are likely very low in the TFT environment and that future studies should target the measurement of HBr or atomic Br.

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Oceanography 70%
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National Center for Atmospheric Research97f103bf-5d6d-4f4d-a978-1c942f9dd2718 d agoJSON v1
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concepts[field].anzsrc:group:3708enrichment · data ucar edutaxonomy-embedding@1.1.0title+keywords+description (70%)
concepts[field].local:field:earth-environmentalmapping · data ucar educonnector:data_ucar_edu@1.0.0
concepts[field].local:field:ocean-atmosphericmapping · data ucar educonnector:data_ucar_edu@1.0.0
created_datesource · data ucar educonnector:data_ucar_edu@1.0.0
descriptionsource · data ucar educonnector:data_ucar_edu@1.0.0/notes
publication_datesource · data ucar educonnector:data_ucar_edu@1.0.0
titlesource · data ucar educonnector:data_ucar_edu@1.0.0/title
updated_datesource · data ucar educonnector:data_ucar_edu@1.0.0