Data · collection · 2015
Determination of Kepone and Its Metabolite in Water and Soil by High-Performance Liquid Chromatography–Mass Spectrometry
Listed in DataCite
Kepone (chlordecone) is a persistent organic pollutant and may degrade to kepone alcohol.
Description
A fast and sensitive high-performance liquid chromatography–electrospray ionization–mass spectrometry (HPLC–ESI–MS) method using multiple reaction monitoring is reported for the accurate determination of kepone and kepone alcohol. Water and soil were enriched by liquid–liquid extraction and liquid–solid extraction.
Good linearity was obtained between 1 and 100 ng/mL with r 2 = 0.997 for kepone and 30 and 200 ng/mL with r 2 = 0.996 for kepone alcohol. The recovery was in the range of 70% to 90%. This approach provided higher sensitivity compared to gas chromatography methods and avoided the formation of an artifact methanolic hemiketal.
Links
Where it is published
- Repository landing page tandf.figshare.com/collections/Determination_of_Kepone_and_Its_Metabolite_in_Wate… ↗
landing page · from DataCite
- Repository landing page tandf.figshare.com/collections/Determination_of_Kepone_and_Its_Metabolite_in_Wate… ↗
landing page · from DataCite
- DOI doi.org/10.6084/m9.figshare.c.1999646 ↗
DOI / persistent id · from DataCite
- DOI doi.org/10.6084/m9.figshare.c.1999646.v1 ↗
DOI / persistent id · from DataCite
Documentation and papers
Catalogue records · 4
- DataCite API api.datacite.org/dois/10.6084/m9.figshare.c.1999646.v1 ↗
metadata API · from DataCite
- DataCite API api.datacite.org/dois/10.6084/m9.figshare.c.1999646 ↗
metadata API · from DataCite
- DataCite Commons commons.datacite.org/doi.org/10.6084/m9.figshare.c.1999646.v1 ↗
catalogue entry · from DataCite
- DataCite Commons commons.datacite.org/doi.org/10.6084/m9.figshare.c.1999646 ↗
catalogue entry · from DataCite
Topics
- Stated by source
- Biological sciences · Biological sciences · Clinical medicine · Clinical medicine
- From keywords
- Chemistry · Chemistry · Ecology · Immunology · Life Sciences · Life Sciences · Microbiology
- Inferred from text
- Mass spectrometry 75%
Provenance · 2 source records, 16 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| DataCite | 10.6084/m9.figshare.c.1999646 | 15 d ago | JSON v1 |
| DataCite | 10.6084/m9.figshare.c.1999646.v1 | 15 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| access_level | source · DataCite | connector:datacite@1.0.0 | /data/attributes/rightsList |
| concepts[field].fos:biological-sciences | source · DataCite | connector:datacite@1.0.0 | |
| concepts[field].fos:biological-sciences | source · DataCite | connector:datacite@1.0.0 | |
| concepts[field].fos:clinical-medicine | source · DataCite | connector:datacite@1.0.0 | |
| concepts[field].fos:clinical-medicine | source · DataCite | connector:datacite@1.0.0 | |
| concepts[field].local:field:chemistry | mapping · DataCite | vocabulary-mapper@1.0.0 | keywords['Chemistry'] |
| concepts[field].local:field:chemistry | mapping · DataCite | vocabulary-mapper@1.0.0 | keywords['Chemistry'] |
| concepts[field].local:field:life-sciences | mapping · DataCite | vocabulary-mapper@1.0.0 | keywords['Biological Sciences'] |
| concepts[field].local:field:life-sciences | mapping · DataCite | vocabulary-mapper@1.0.0 | keywords['Biological Sciences'] |
| concepts[modality].local:modality:mass-spectrometry | enrichment · DataCite | keyword-concept-rules@1.0.0 | title+description (75%) |
| created_date | source · DataCite | connector:datacite@1.0.0 | |
| description | source · DataCite | connector:datacite@1.0.0 | /data/attributes/descriptions |
| license | source · DataCite | connector:datacite@1.0.0 | /data/attributes/rightsList |
| publication_date | source · DataCite | connector:datacite@1.0.0 | /data/attributes/dates |
| title | source · DataCite | connector:datacite@1.0.0 | /data/attributes/titles/0/title |
| updated_date | source · DataCite | connector:datacite@1.0.0 |