Data for Two-dimensional ketone-driven metal–organic coordination on Cu(111)

The strongly electronegative ketone moieties bind to either copper adatoms from the substrate or co-deposited iron atoms. In the former case, scanning tunnelling microscopy images reveal the development of an extended metal-organic supramolecular structure.

Each copper adatom coordinates two ketone ligands of two neighbouring PTO molecules, forming chains that are linked together into large islands via secondary van der Waals interactions. Deposition of iron atoms leads to a transformation of this assembly resulting from the substitution of the metal centres. Density functional theory calculations reveal that the driving force for the metal substitution is primarily determined by the strength of the ketone-metal bond, which is higher for Fe compared to Cu.