1.3cm line survey toward Orion KL

Non-metastable ^15^NH_3_ transitions are detected in Orion KL for the first time. Based on the velocity information of detected lines and the ALMA images, the spatial origins of molecular emission are constrained and discussed. A narrow feature is found in SO_2_ (8_1,7_-7_2,6_), possibly suggesting the presence of a maser line.

Column densities and fractional abundances relative to H_2_ are estimated for 12 molecules with LTE methods. Rotational diagrams of non-metastable ^14^NH_3_ transitions with J=K+1 to J=K+4 yield different results; metastable ^15^NH_3_ is found to have a higher excitation temperature than non-metastable ^15^NH_3_, indicating that they may trace different regions. Elemental and isotopic abundance ratios are estimated: ^12^C/^13^C=63+/-17, ^14^N/^15^N=100+/-51, D/H=0.0083+/-0.0045.

The dispersion of the He/H ratios derived from H_alpha/He_alpha_ pairs to H_delta_/He_delta_ pairs is very small, which is consistent with theoretical predictions that the departure coefficients bn factors for hydrogen and helium are nearly identical. Based on a non-LTE code neglecting excitation by the infrared radiation field and a likelihood analysis, we find that the denser regions have lower kinetic temperature, which favors an external heating of the Hot Core.