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Structure · dataset · 2019

Hydrothermal Synthesis to Water-stable Luminescent Carbon Dots from Acerola Fruit for Photoluminescent Composites Preparation and its Application as Sensors

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Carbon dots (C-dots) possess the attractive properties of high stability, low toxicity, good water solubility, simple synthetic routes as well as size and excitation-dependent photoluminescence (PL).The aim of this work was to synthesize photoluminescent C-dots by hydrothermal method using acerola fruit (Malpighiaemarginata) as a row material, since this fruit contains large number of organic molecules. Studies about the optimal synthesis conditions were performed, where these organic molecules were converted into C-dots by hydrothermal carbonization at 180 ºC for 18 h.

The C-dots exhibited a green emission light at 459 nm when excited under UV-light ( λ ex= 370 nm). These nanomaterials were also successfully used to prepare C-dots/poly (vinyl alcohol) luminescent composites (C-dots/PVA). Both C-dots and C-dots/PVA composite films were investigated by using colorimetric visual sensor for Fe3+ metal ions detection.

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The results show that the prepared C-dots and C-dots/poly presented strong green emission light. The emission spectra of above materials were quenched in the presence of Fe3+ ions. Thus, highly specific “turn off” fluorescence sensing of Fe3+ was achieved using fluorescent C-dots.

Regarding, this work describe that the polymeric films as sensors of metallic ions in aqueous solution appears as a new perspectives to design new composite materials.

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Inorganic chemistry 69%

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DataCite10.6084/m9.figshare.8259941.v113 d agoJSON v1
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