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Data · dataset · 2026

Photochemistry on the bottom side of the mesospheric Na layer

Listed in National Center for Atmospheric Research

Lidar observations of the mesospheric Na layer have revealed considerable diurnal variations, particularly on the bottom side of the layer, where more than an order-of-magnitude increase in Na density has been observed below 80 km after sunrise.

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In this paper, multi-year Na lidar observations are utilized over a full diurnal cycle at Utah State University (USU) (41.8 degrees N, 111.8 degrees W) and a global atmospheric model of Na with 0.5 km vertical resolution in the mesosphere and lower thermosphere (WACCM-Na) to explore the dramatic changes of Na density on the bottom side of the layer.

Photolysis of the principal reservoir NaHCO3 is shown to be primarily responsible for the increase in Na after sunrise, amplified by the increased rate of reaction of NaHCO3 with atomic H, which is mainly produced from the photolysis of H2O and the reaction of OH with O-3. This finding is further supported by Na lidar observation at USU during the solar eclipse (> 96% totality) event on 21 August 2017, when a decrease and recovery of the Na density on the bottom side of the layer were observed.

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Lastly, the model simulation shows that the Fe density below around 80 km increases more strongly and earlier than observed Na changes during sunrise because of the considerably faster photolysis rate of its major reservoir of FeOH.

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National Center for Atmospheric Research60225e0a-6f01-4326-b1d8-bcd53df7531f10 d agoJSON v1
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concepts[field].local:field:ocean-atmosphericmapping · data ucar educonnector:data_ucar_edu@1.0.0
concepts[method].local:method:simulationenrichment · data ucar edukeyword-concept-rules@1.0.0title+description (75%)
created_datesource · data ucar educonnector:data_ucar_edu@1.0.0
descriptionsource · data ucar educonnector:data_ucar_edu@1.0.0/notes
publication_datesource · data ucar educonnector:data_ucar_edu@1.0.0
titlesource · data ucar educonnector:data_ucar_edu@1.0.0/title
updated_datesource · data ucar educonnector:data_ucar_edu@1.0.0