Table · dataset · 2025
Dataset of the work “Electrochemically generated CuI and CuSCN nanocrystals on Cu surfaces as Raman enhancing substrates”
Listed in Repositorio Institucional de la Universidad de Burgos
Raman enhancing strategies, such as Surface-Enhance Raman scattering (SERS), are a key piece for the development of spectroscopic and analytical strategies based on Raman spectroscopy, due to the intrinsic low sensitivity of the Raman scattering.
Description
Some years ago, our group reported an unexpected Raman enhancement process observed during the electrochemical oxidation of metallic electrodes, named Electrochemical Oxidation Surface-Enhanced Raman scattering (EC-SOERS).
This Raman enhancement phenomenon was recently explained as an interaction of the analyte and the SERS dielectric substrate promoted by a metal cation. The elucidation of the origin of this enhancement is now leading to the development of new Raman enhancing substrates, such as copper-based substrates. In this work, we present an overview of the use of copper electrodes as EC-SOERS substrates.
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The presented strategies allow the electrosynthesis of SERS-active CuI nanocrystals on a metallic copper surface, which provides Raman enhancement for a wide number of molecules. The influence of the electrochemical conditions and the structure of the studied molecules are discussed. The use of CuSCN nanocrystals is also explored as substrates to promote Raman enhancement.
Links
Where it is published
- hdl.handle.net /10259/10751 ↗
Repositorio Institucional de la Universidad de Burgos record
landing page · from riubu ubu es
- DOI doi.org/10.71486/ddhq-6147 ↗
DOI / persistent id · from riubu ubu es
Catalogue records · 1
- OAI-PMH record riubu.ubu.es/oai/request%20?verb=GetRecord&metadataPrefix=oai_dc&identifier… ↗
metadata API · from riubu ubu es
Topics
- From keywords
- Chemistry · Earth & Environmental Science · Electrochemistry · Engineering · Humanities · Life Sciences · Social Science
Provenance · 1 source records, 13 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| Repositorio Institucional de la Universidad de Burgos | oai:riubu.ubu.es:10259/10751 | 9 d ago | JSON v1 |
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|---|---|---|---|
| access_level | source · riubu ubu es | connector:riubu_ubu_es@1.0.0 | |
| concepts[field].anzsrc:field:340604 | mapping · riubu ubu es | vocabulary-mapper@1.0.0 | keywords['Electrochemistry'] |
| concepts[field].local:field:chemistry | mapping · riubu ubu es | connector:riubu_ubu_es@1.0.0 | |
| concepts[field].local:field:earth-environmental | mapping · riubu ubu es | connector:riubu_ubu_es@1.0.0 | |
| concepts[field].local:field:engineering | mapping · riubu ubu es | connector:riubu_ubu_es@1.0.0 | |
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| concepts[field].local:field:life-sciences | mapping · riubu ubu es | connector:riubu_ubu_es@1.0.0 | |
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| description | source · riubu ubu es | connector:riubu_ubu_es@1.0.0 | /metadata/dc/description |
| license | source · riubu ubu es | connector:riubu_ubu_es@1.0.0 | /metadata/dc/rights |
| publication_date | source · riubu ubu es | connector:riubu_ubu_es@1.0.0 | |
| spatial | source · riubu ubu es | connector:riubu_ubu_es@1.0.0 | |
| title | source · riubu ubu es | connector:riubu_ubu_es@1.0.0 | /metadata/dc/title |