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Hydroxylamine as a potential indicator of nitrification in the open ocean

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Hydroxylamine (NH 2 OH), a short-lived intermediate in the nitrogen cycle, is a potential precursor of nitrous oxide (N 2 O) in the ocean.

Description

However, measurements of NH 2 OH in the ocean are sparse. Here we present a data set of depth profiles of NH 2 OH from the equatorial Atlantic Ocean and the eastern tropical South Pacific and compare it to N 2 O, nitrate, and nitrite profiles under varying oxygen conditions.

The presence of NH 2 OH in surface waters points toward surface nitrification in the upper 100 m. Overall, we found a ratio of 1:3 between NH 2 OH and N 2 O in open ocean areas when oxygen concentrations were >50 μmol/L. In the equatorial Atlantic Ocean and the open ocean eastern tropical South Pacific, where nitrification is the dominant N 2 O production pathway, stepwise multiple regressions demonstrated that N 2 O, NH 2 OH, and nitrate concentrations were highly correlated, suggesting that NH 2 OH is a potential indicator for nitrification.

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Inferred from text
Pollution and contamination 69%
Provenance · 1 source records, 8 field assertions
SourceKeyLast seenRaw
PANGAEAoai:pangaea.de:doi:10.1594/PANGAEA.90801214 d agoJSON v1
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concepts[field].anzsrc:group:4105enrichment · PANGAEAtaxonomy-embedding@1.1.0title+keywords+description (69%)
concepts[field].local:field:earth-environmentalmapping · PANGAEAconnector:pangaea@1.0.0
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