Data · collection · 2016
Syntheses and structures of two new lithium-heptamolybdates
Listed in DataCite
The synthesis, crystal structures, IR, UV–vis, 7 Li NMR spectra, electrochemical investigations, and conductivity studies of two new lithium-heptamolybdates, (NH 4 ) 4 [Li 2 (H 2 O) 7 ][Mo 7 O 24 ]·H 2 O ( 1 ) and (NH 4 ) 3 [Li 3 (H 2 O) 4 ( μ 6 -Mo 7 O 24 )]·2H 2 O ( 2 ), are reported.
Description
In 1 the (NH 4 ) + and [Li 2 (H 2 O) 7 ] 2+ , cations are charge balanced by the heptamolybdate anion. In 2 , the [Mo 7 O 24 ] 6− anion is coordinated to three unique Li + ions via a μ 6 -hexadentate-binding mode resulting in the formation of a two-dimensional (2-D) [Li 3 (H 2 O) 4 ( μ 6 -Mo 7 O 24 )] 3− anionic complex, charge neutralized by three (NH 4 ) + ions.
The cations, anions, and the lattice water molecules in 1 and 2 are linked by weak H-bonding interactions.
Links
Where it is published
- Repository landing page figshare.com/collections/Syntheses_and_structures_of_two_new_lithium_heptam… ↗
landing page · from DataCite
- DOI doi.org/10.6084/m9.figshare.c.2849971.v1 ↗
DOI / persistent id · from DataCite
Documentation and papers
- CC-BY creativecommons.org/licenses/by/3.0/us ↗
license · from DataCite
- IsSupplementTo 10.1080/00958972.2016.1159679 doi.org/10.1080/00958972.2016.1159679 ↗
publication · from DataCite
Catalogue records · 2
- DataCite API api.datacite.org/dois/10.6084/m9.figshare.c.2849971.v1 ↗
metadata API · from DataCite
- DataCite Commons commons.datacite.org/doi.org/10.6084/m9.figshare.c.2849971.v1 ↗
catalogue entry · from DataCite
Topics
- Stated by source
- Biological sciences · Chemical sciences · Clinical medicine · Physical sciences
- From keywords
- Biochemistry and cell biology · Immunology · Plant biology
Related
Provenance · 1 source records, 11 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| DataCite | 10.6084/m9.figshare.c.2849971.v1 | 14 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| access_level | source · DataCite | connector:datacite@1.0.0 | /data/attributes/rightsList |
| concepts[field].fos:biological-sciences | source · DataCite | connector:datacite@1.0.0 | |
| concepts[field].fos:chemical-sciences | source · DataCite | connector:datacite@1.0.0 | |
| concepts[field].fos:clinical-medicine | source · DataCite | connector:datacite@1.0.0 | |
| concepts[field].fos:physical-sciences | source · DataCite | connector:datacite@1.0.0 | |
| created_date | source · DataCite | connector:datacite@1.0.0 | |
| description | source · DataCite | connector:datacite@1.0.0 | /data/attributes/descriptions |
| license | source · DataCite | connector:datacite@1.0.0 | /data/attributes/rightsList |
| publication_date | source · DataCite | connector:datacite@1.0.0 | /data/attributes/dates |
| title | source · DataCite | connector:datacite@1.0.0 | /data/attributes/titles/0/title |
| updated_date | source · DataCite | connector:datacite@1.0.0 |