Data · collection · 2015

Syntheses and Crystal Structure of Three Novel Supramolecular Halides/Pseudohalides {(DMB)[Cu 2 (SCN) 4 ]} n, {(DMB)[Cu(SCN) 4 ]}, and {(DMB)[Ag 2 (SCN) 4 ]} n Directed by Dicationic Template Possessing C2-Symmetry

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Three novel hybrid complexes, namely{(DMB)[Cu 2 (SCN) 4 ]} n ( 1 ), {(DMB)[Cu(SCN) 4 ]} ( 2 ), and {(DMB)[Ag 2 (SCN) 4 ]} n ( 3 ), have been synthesized via the self-assembly in DMF–methanol system based on multidentate ligand DMB, {DMB = α, α ′ - di(3-methylimidozole-1-yl)benzene dichloride}.