Heavy element abundances in giant stars

We confirm and expand on previous results for these clusters by showing that (1) all elements heavier than, and including, Si have constant abundances within each cluster, (2) the elements from Ca to Ni have indistinguishable compositions in M4 and M5, (3) Si, Cu, Zn, and all s-process elements are approximately 0.3dex overabundant in M4 relative to M5, and (4) the r-process elements Sm, Eu, Gd, and Th are slightly overabundant in M5 relative to M4.

The cluster-to-cluster abundance differences for Cu and Zn are intriguing, especially in light of their uncertain nucleosynthetic origins. We confirm that stars other than Type Ia supernovae must produce significant amounts of Cu and Zn at or below the clusters' metallicities. If intermediate-mass AGB stars or massive stars are responsible for the Cu and Zn enhancements in M4, the similar [Rb/Zr] ratios and (preliminary) Mg isotope ratios in both clusters may be problematic for either scenario.