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Data · collection · 2016

Solvent-dependent moulding of porphyrin-based nanostructures: solid state, solution and on surface self-assembly

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A novel porphyrin derivative 1∙Zn was synthesised in order to mimic the self-assembly properties of natural light-harvesting antennas and its self-assembly behaviour in solution and in solid state were studied by NMR and X-Ray spectroscopies.

Description

The self-assembly of this molecule was triggered in apolar solvents and studied in solution by UV-Vis spectroscopy, suggesting it is able to form slipped face-to-face aggregates, or J -aggregates.

The nanoscopic and microscopic morphology of the aggregates was elucidated by atomic force microscopy, revealing the formation of extended two-dimensional structures.

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Microscopy 75%
Provenance · 1 source records, 11 field assertions
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DataCite10.6084/m9.figshare.c.285823612 d agoJSON v1
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concepts[modality].local:modality:microscopyenrichment · DataCitekeyword-concept-rules@1.0.0title+description (75%)
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