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Archive · collection · 2000

Amino acid concentrations in interstitial waters from ODP Sites 113-689 and 113-690

Listed in PANGAEA and DataCite — shown once because both records carry DOI 10.1594/pangaea.726857

Biogenic calcareous and siliceous sediments were drilled at ODP Sites 689 and 690 on the Maud Rise, Antarctic Ocean.

Description

We analyzed dissolved combined amino acids (DCAA) and dissolved free amino acids (DFAA) in interstitial waters in order to characterize the amino acids in dissolved organic matter. The DFAA was predominant over the DCAA in interstitial waters at Sites 689 and 690, which contradicted the previous results from interstitial water and seawater studies.

The DCAA in the interstitial waters probably originated from calcareous biogenic debris with less amounts of siliceous debris. Although glutamic acid constituted 41% of the total concentration of DCAA, it accounted for only 1% of the total concentration of DFAA due to the adsorption and/or reaction with biogenic carbonate. Ornithine, a nonprotein amino acid, is a decomposed product of arginine and made up 17 mol% of the total DFAA and.

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The total hydrolyzable amino acids (=DCAA + DFAA) accounted for 5 to 28% of the dissolved organic carbon (DOC) concentration, which implied that high molecular weight organic matter was a major contributor for the DOM (dissolved organic matter) in interstitial waters. Fairly positive correlation between the dissolved manganese and the total DCAA values suggested that the redox condition plays a significant role in controlling the total DCAA content.

A small decrease in the sulfate concentration in the interstitial waters from both sites suggested fairly low microbial activity by sulfate-reducing bacteria.

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Provenance · 2 source records, 7 field assertions
SourceKeyLast seenRaw
PANGAEAoai:pangaea.de:doi:10.1594/PANGAEA.72685714 d agoJSON v1
DataCite10.1594/pangaea.72685714 d agoJSON v1
FieldAssertionExtractorEvidence
access_levelsource · PANGAEAconnector:pangaea@1.0.0
concepts[field].local:field:earth-environmentalmapping · PANGAEAconnector:pangaea@1.0.0
descriptionsource · PANGAEAconnector:pangaea@1.0.0/metadata/dc/description
licensesource · PANGAEAconnector:pangaea@1.0.0/metadata/dc/rights
publication_datesource · PANGAEAconnector:pangaea@1.0.0
spatialsource · PANGAEAconnector:pangaea@1.0.0
titlesource · PANGAEAconnector:pangaea@1.0.0/metadata/dc/title