Research data for "Trioxanes as photodegradable motifs for additive manufacturing"

Tab 5: "Figure 5": Tensile testing and dynamic mechanical analysis (DMTA) data of N-PAG and L-PAG Tab 6: "Figure S1": NMR data of trioxane Tab 7: "Figure S2": NMR data of reference aldehyde Tab 8: "Figure S3": Photorheology data (irradiation with LED light source) of N-PAG and L-PAG Tab 9: "Figure S4": ATR-IR data of trioxane and 10-undecanal Tab 10: "Figure S5": DMTA and ATR-IR data of L-PAG formulation (uncured), L-PAG material (cured in Lumamat), A-PAG material directly after UV irradiation (after Uvitron) or after UV irradiation and subsequent DMTA measurement (after DMTA, polymeric/liquid part) Tab 11: "Figure S6": ATR-IR data of aged (110 days) L-PAG material compared to fresh and aged A-PAG and reference aldehyde The compound abbreviations/descriptions in the Excel file are described in the following: Small molecules: TPO-L: Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate (radical photoinitiator) PAG: photoacid generator UVI6976 (mixture of triarylsulfonium hexafluoroantimonate salts in propylene carbonate) trioxane : trioxane-containing triene utilized as crosslinker ( 1,3,5-trioxane-2,4,6-tris(9-decenyl) ) trixoane+PAG : trioxane-containing triene utilized as crosslinker mixed with PAG, not irradiated trioxane+PAG+UV: trioxane-containing triene utilized as crosslinker mixed with PAG, irradiated with ultraviolet (UV) light (Uvitron International INTELLIRAY 600 UV-oven; 320-500 nm Hg broadband UV lamp; 600 W; UV-A: 125 mW cm-2; vis: 125 mW cm-2, 300 s on both sides at 100% intensity) 10-undecanal: reference compound for the small molecule degradation study reference aldehyde : model compound for trioxane degradation product for the material degradation study CHTT : trithiol comonomer ( 1,2,4-cyclohexanetriethanethiol) Materials: All materials consist of a thiol-ene network consisting of equimolar amounts of trioxane and CHTT photopolymerized by TPO-L (1 wt%) and BHT (0.2 wt%).

Inclusion of the PAG UVI6976 (1 wt%) in the network and its irradiation condition is indicated in the following material abbreviations: N-PAG = No PAG : PAG was not added to the formulation/material L-PAG = inactive PAG : Formulation/material contains PAG but was not UV irradiated with the UV-oven A-PAG : Material contains PAG, which was activated by UV irradiation in the UV-oven as described above NMR data included in the Excel file has additionally been added as raw data files (Bruker) in the folder "NMR data" , which can be opened with community-standard programmes (e.g. MestRe Nova, TopSpin).