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Data · collection · 2016

Regiospecific Synthesis of Dimethylphenanthrenes

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Description

The dimethylated phenanthrenes 2,3-dimethylphenanthrene ( 4a ), 2,7-dimethylphenanthrene ( 4b ), 2,6-dimethylphenanthrene ( 4c ) and 1,7-dimethylphenanthrene ( 4d ) have been prepared in gram-quantities by a short sequence of directed ortho metalation (DoM) of N,N-diethylbenzamides followed by Suzuki–Miyaura cross-coupling reaction and directed remote metalation (DreM) to form 9-phenanthrols. The final phenanthrenes were obtained through protection/deprotection as triflates.

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Provenance · 1 source records, 14 field assertions
SourceKeyLast seenRaw
DataCite10.6084/m9.figshare.c.324741412 d agoJSON v1
FieldAssertionExtractorEvidence
access_levelsource · DataCiteconnector:datacite@1.0.0/data/attributes/rightsList
concepts[field].fos:biological-sciencessource · DataCiteconnector:datacite@1.0.0
concepts[field].fos:chemical-sciencessource · DataCiteconnector:datacite@1.0.0
concepts[field].fos:earth-and-related-environmental-sciencessource · DataCiteconnector:datacite@1.0.0
concepts[field].fos:physical-sciencessource · DataCiteconnector:datacite@1.0.0
concepts[field].fos:sociologysource · DataCiteconnector:datacite@1.0.0
concepts[field].local:field:medicine-healthmapping · DataCitevocabulary-mapper@1.0.0keywords['Medicine']
concepts[field].local:field:social-sciencemapping · DataCitevocabulary-mapper@1.0.0keywords['Sociology']
created_datesource · DataCiteconnector:datacite@1.0.0
descriptionsource · DataCiteconnector:datacite@1.0.0/data/attributes/descriptions
licensesource · DataCiteconnector:datacite@1.0.0/data/attributes/rightsList
publication_datesource · DataCiteconnector:datacite@1.0.0/data/attributes/dates
titlesource · DataCiteconnector:datacite@1.0.0/data/attributes/titles/0/title
updated_datesource · DataCiteconnector:datacite@1.0.0