AlI and AlII extended transition rates

In AlI the configurations of interest are 3s^2^nl for n=3,4,5 with l=0 to 4, as well as 3s3p^2^ and 3s^2^6l for l=0,1,2. In AlII, in addition to the ground configuration 3s^2^, the studied configurations are 3snl with n=3 to 6 and l=0 to 5, 3p^2^, 3s7s, 3s7p, and 3p3d.

Valence and core-valence electron correlation effects are systematically accounted for through large configuration state function (CSF) expansions. Calculated excitation energies are found to be in excellent agreement with experimental data from the National Institute of Standards and Technology (NIST) database. Lifetimes and transition data for radiative electric dipole (E1) transitions are given and compared with results from previous calculations and available measurements for both AlI and AlII.