In situ Raman investigation of Dy complexation in Cl-bearing aqueous solutions at 20–300 °C

In this study, the speciation of Dy in acidic chloride-bearing hydrothermal solutions was investigated using confocal Raman spectroscopy with a new capillary Raman heating stage at 20–300 °C. Background solutions (pure water, NaCl-solutions) and solutions with 0.14–1.8 mol kg−1 dissolved DyCl3 were sealed in quartz capillary cells. Comparison of the spectra for Dy chloride solutions with those for background solutions and the spectra for reference Dy-bearing solids was used to identify Raman bands specific to Dy–O and Dy–Cl bonds.

The Raman band for the Dy–O stretching mode of hydrated Dy3+ aqua ions was measured at 365–384 cm−1 and a Raman band for the Dy–Cl stretching modes of Dy chloride complexes was measured near 240 cm−1 . The Dy–O band decreases systematically with temperature, whereas the Dy–Cl band systematically increases, indicating a systematic increase in the stability of Dy chloride complexes with temperature. This study provides the framework for expanding the use of in situ Raman spectroscopy to investigate the speciation of REE in aqueous solutions to hydrothermal conditions.