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Data · dataset · 2026

Validation of MIPAS ClONO₂ measurements

Listed in National Center for Atmospheric Research

Description

Altitude profiles of ClONO2 retrieved with the IMK (Institut für Meteorologie und Klimaforschung) science-oriented data processor from MIPAS/Envisat (Michelson Interferometer for Passive Atmospheric Sounding on Envisat) mid-infrared limb emission measurements between July 2002 and March 2004 have been validated by comparison with balloon-borne (Mark IV, FIRS2, MIPAS-B), airborne (MIPAS-STR), ground-based (Spitsbergen, Thule, Kiruna, Harestua, Jungfraujoch, Izaña, Wollongong, Lauder), and spaceborne (ACE-FTS) observations.

With few exceptions we found very good agreement between these instruments and MIPAS with no evidence for any bias in most cases and altitude regions. For balloon-borne measurements typical absolute mean differences are below 0.05 ppbv over the whole altitude range from 10 to 39 km. In case of ACE-FTS observations mean differences are below 0.03 ppbv for observations below 26 km.

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Above this altitude the comparison with ACE-FTS is affected by the photochemically induced diurnal variation of ClONO₂. Correction for this by use of a chemical transport model led to an overcompensation of the photochemical effect by up to 0.1 ppbv at altitudes of 30–35 km in case of MIPAS-ACE-FTS comparisons while for the balloon-borne observations no such inconsistency has been detected. The comparison of MIPAS derived total column amounts with ground-based observations revealed no significant bias in the MIPAS data.

Mean differences between MIPAS and FTIR column abundances are 0.11±0.12×10 14 cm -2 (1.0±1.1%) and −0.09±0.19×10 14 cm -2 (−0.8±1.7%), depending on the coincidence criterion applied. x² tests have been performed to assess the combined precision estimates of MIPAS and the related instruments. When no exact coincidences were available as in case of MIPAS--FTIR or MIPAS--ACE-FTS comparisons it has been necessary to take into consideration a coincidence error term to account for x² deviations.

From the resulting x² profiles there is no evidence for a systematic over/underestimation of the MIPAS random error analysis.

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National Center for Atmospheric Research847c1c7b-efec-4c5c-a760-6b1b67b5618210 d agoJSON v1
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concepts[field].local:field:earth-environmentalmapping · data ucar educonnector:data_ucar_edu@1.0.0
concepts[field].local:field:ocean-atmosphericmapping · data ucar educonnector:data_ucar_edu@1.0.0
created_datesource · data ucar educonnector:data_ucar_edu@1.0.0
descriptionsource · data ucar educonnector:data_ucar_edu@1.0.0/notes
publication_datesource · data ucar educonnector:data_ucar_edu@1.0.0
titlesource · data ucar educonnector:data_ucar_edu@1.0.0/title
updated_datesource · data ucar educonnector:data_ucar_edu@1.0.0