Data · dataset · 2026
Determination of the atmospheric lifetime and global warming potential of sulfur hexafluoride using a three-dimensional model
Listed in National Center for Atmospheric Research
We have used the Whole Atmosphere Community Climate Model (WACCM), with an updated treatment of loss processes, to determine the atmospheric lifetime of sulfur hexafluoride (SF6).
Description
The model includes the following SF6 removal processes: photolysis, electron attachment and reaction with mesospheric metal atoms. The Sodankyla Ion Chemistry (SIC) model is incorporated into the standard version of WACCM to produce a new version with a detailed D region ion chemistry with cluster ions and negative ions.
This is used to determine a latitude-and altitude-dependent scaling factor for the electron density in the standard WACCM in order to carry out multi-year SF6 simulations. The model gives a mean SF6 lifetime over an 11-year solar cycle (tau) of 1278 years (with a range from 1120 to 1475 years), which is much shorter than the currently widely used value of 3200 years, due to the larger contribution (97.4 %) of the modelled electron density to the total atmospheric loss.
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The loss of SF6 by reaction with mesospheric metal atoms (Na and K) is far too slow to affect the lifetime. We investigate how this shorter atmospheric lifetime impacts the use of SF6 to derive stratospheric age of air. The age of air derived from this shorter lifetime SF6 tracer is longer by 9% in polar latitudes at 20 km compared to a passive SF6 tracer.
We also present laboratory measurements of the infrared spectrum of SF6 and find good agreement with previous studies. We calculate the resulting radiative forcings and efficiencies to be, on average, very similar to those reported previously. Our values for the 20-, 100-and 500-year global warming potentials are 18 000, 23 800 and 31 300, respectively.
Links
Get the data
- Publisher page n2t.org/ark:/85065/d70z752d ↗
documentation · download · from data ucar edu
Where it is published
- data.ucar.edu /dataset/determination-of-the-atmospheric-lifetime-and-global-w… ↗
National Center for Atmospheric Research dataset page
landing page · from data ucar edu
Catalogue records · 1
- CKAN API data.ucar.edu/api/3/action/package_show?id=1e21a794-7226-40b1-bfb7-b34e123f9… ↗
metadata API · from data ucar edu
Topics
- From keywords
- Earth & Environmental Science · Ocean & Atmospheric Science
- Inferred from text
- Climate model simulation 65%
Provenance · 1 source records, 8 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| National Center for Atmospheric Research | 1e21a794-7226-40b1-bfb7-b34e123f9269 | 9 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| concepts[field].local:field:earth-environmental | mapping · data ucar edu | connector:data_ucar_edu@1.0.0 | |
| concepts[field].local:field:ocean-atmospheric | mapping · data ucar edu | connector:data_ucar_edu@1.0.0 | |
| concepts[method].local:method:climate-model | enrichment · data ucar edu | keyword-concept-rules@1.0.0 | title+description (65%) |
| created_date | source · data ucar edu | connector:data_ucar_edu@1.0.0 | |
| description | source · data ucar edu | connector:data_ucar_edu@1.0.0 | /notes |
| publication_date | source · data ucar edu | connector:data_ucar_edu@1.0.0 | |
| title | source · data ucar edu | connector:data_ucar_edu@1.0.0 | /title |
| updated_date | source · data ucar edu | connector:data_ucar_edu@1.0.0 |