Data for High-throughput tertiary amine deoxygenated photopolymerizations for synthesizing polymer libraries

This removed all reaction components yielding pure polymers, which is not easily achieved with systems using metal catalysts and secondary reductants, such as ascorbic acid. As an example of the throughput, in just under 40 h, 392 polymers were synthesized and subsequently analyzed direct from plates by a 96-well plate sampling size exclusion chromatography system to demonstrate reproducibility. Due to less efficient degassing in dioxane (compared to DMSO), the molecular weight and dispersity control were limited in some cases (with acrylates giving the lowest dispersities), but the key aim of this system is to access hundreds of polymers quickly and in a format needed to enable testing.

This method enables easy exploration of chemical space and development of screening libraries to identify hits for further study using precision polymerization methods.<br><br>WRAP data for High-Throughput Tertiary Amine De-oxygenated Photopolymerizations for Synthesizing Polymer Libraries -Constant radical concentration – Raw data for figure 3 -Conversion – Raw data for figures 5 -Headspace – Raw data for experiements varying the headspace of the reaction vessel (not applicable figure) -Molecular Weight Control – Raw data for figure 4 -Monomer Content – Raw data for figure 4 -Multi Monomer Raw data – Raw data for figure 4 -TEOA – Raw data for figure 2 -TEOA Removal – Raw data for figure 5