Structure · dataset · 2022
Effect of Fe3O4@PDA morphology on the U(VI) entrapment from aqueous solution-dataset
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Two kinds of core–shell Fe3O4@PDA materials with different morphologies were successfully prepared by a simple in situ polymerization method based on two kinds of pristine Fe3O4 spheres, which were obtained by hydrothermal method.
Description
Among the four obtained samples, Fe3O4@PDA porous nano-spheres (MNS-4) have the best U(VI) entrapment performance, which can not only be owing to the structure characteristics (higher porosity and lower density) but also to the PDA shell with large amount of functional groups.
Additionally, the maximum removal capacity of MNS-4 for U(VI) entrapment can be of 193.27 mg·g−1 at 298 K, which exceeds the adsorption capacity of most other reported magnetic materials. Moreover, the solution pH values have a significant effect on the adsorption performance of the adsorbents for U(VI) pre-concentration while that originated from ionic strength can be negligible, suggesting that the adsorption process can be achieved through inner-sphere surface complexation.
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Thermodynamic studies reveal that the U(VI) adsorption process is exothermic and spontaneous. The analysis of adsorption mechanism indicates that U(VI) pre-concentration process can be achieved by the interactions between OH groups, pyridinic N and CNH2 and U(VI)
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Where it is published
- DOI doi.org/10.57760/sciencedb.04059 ↗
DOI / persistent id · from scidb cn
Catalogue records · 1
- OAI-PMH record scidb.cn/oai?verb=GetRecord&metadataPrefix=oai_dc&identifier=10.57760%2… ↗
metadata API · from scidb cn
Topics
- From keywords
- Earth & Environmental Science · Engineering · Humanities · Life Sciences · Materials Science · Social Science
- Inferred from text
- Nanotechnology 69%
Provenance · 1 source records, 12 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| ScienceDB | 10.57760/sciencedb.04059 | 10 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| access_level | source · scidb cn | connector:scidb_cn@1.0.0 | |
| concepts[field].anzsrc:group:4018 | enrichment · scidb cn | taxonomy-embedding@1.0.0 | title+keywords+description (69%) |
| concepts[field].local:field:earth-environmental | mapping · scidb cn | connector:scidb_cn@1.0.0 | |
| concepts[field].local:field:engineering | mapping · scidb cn | connector:scidb_cn@1.0.0 | |
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| concepts[field].local:field:life-sciences | mapping · scidb cn | connector:scidb_cn@1.0.0 | |
| concepts[field].local:field:materials-science | mapping · scidb cn | connector:scidb_cn@1.0.0 | |
| concepts[field].local:field:social-science | mapping · scidb cn | connector:scidb_cn@1.0.0 | |
| description | source · scidb cn | connector:scidb_cn@1.0.0 | /metadata/dc/description |
| license | source · scidb cn | connector:scidb_cn@1.0.0 | /metadata/dc/rights |
| publication_date | source · scidb cn | connector:scidb_cn@1.0.0 | |
| title | source · scidb cn | connector:scidb_cn@1.0.0 | /metadata/dc/title |