Data for An expanded MIL-53-type coordination polymer with a reactive pendant ligand

A coordination polymer with a structure isoreticular to MIL-53, but containing a divalent metal cation (Co2+ or Mg2+) and a coordinating 4-styrylpyridine-N-oxide ligand, crystallises under solvothermal conditions; the pendant ligand can be brominated, with evidence from powder X-ray diffraction, element mapping and 81Br solid-state NMR for this post-synthesis modification.<br><br>Crystal structure are available from the CCDC using the information provided in the paper.

Thermogravimetric analysis (TGA-DSC in Figure 3a) is provded in an ascii file in x,y1,y2 format: temperature, percentage mass, heat flow Measured powder XRD (Figure 4a) is provided in acsii files in x,y format: angle, intensity.