Characteristics of the atmospheric CO₂ signal as observed over the conterminous United States during INTEX-NA

Clear signatures of CO₂ uptake were seen east of the Mississippi River, notably a persistent CO₂ deficit in the lowest 2 - 3 km. When combining the airborne CO₂ measurements with LANDSAT and MODIS data products, the lowest CO₂ mixing ratios observed during the campaign (337 ppm) were tied to mid-continental agricultural fields planted in corn and soybeans. We used simultaneous measurements of CO, O₃, C₂Cl₄, C₂H₆, C₂H₂ and other unique chemical tracers to differentiate air mass types.

Coupling these distinct air mass chemical signatures with transport history permitted identification of convection, stratosphere-troposphere exchange, long-range transport from Eastern Asia, boreal wildfires, and continental outflow as competing processes at multiple scales influencing the observed concentrations. Our results suggest these are important factors contributing to the large-scale distribution in CO₂ mixing ratios thus these observations offer new constraints in the computation of the North American carbon budget.