Data · collection · 2016
Synthesis, characterization, and insecticidal activity of new tin (IV) complexes
Listed in DataCite
A three-component reaction of dimethyltin dibromide with imidazo[1,2- a ]pyridine, pyridine derivatives, or isoquinoline and allyl bromide in refluxing ethanol affords the ionic complex, bis(1-allylcycloiminium) dimethyltetrabromostannate (II).
Description
The reaction involves N-allylation of cycloimine accompanied by the coordination of two bromide ions with the tin atom of dimethyltin dibromide. The complexes have been characterized by infrared and 1 H NMR, 13 C NMR, and 119 Sn NMR studies.
The X-ray crystal structure analysis of a complex reveals the tin atom to be hexacoordinated and the dimethyltetrabromostannate (II) anion having octahedral geometry. Some of the complexes tested for their insecticidal activity are found to exhibit strong activity against Tribolium castaneum insect with LC 50 ranging from 0.4 to 0.8 ppm.
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Where it is published
- Repository landing page figshare.com/collections/Synthesis_characterization_and_insecticidal_activi… ↗
landing page · from DataCite
- DOI doi.org/10.6084/m9.figshare.c.3264160 ↗
DOI / persistent id · from DataCite
Documentation and papers
- CC-BY creativecommons.org/licenses/by/3.0/us ↗
license · from DataCite
- IsSupplementTo 10.1080/10426507.2015.1130048 doi.org/10.1080/10426507.2015.1130048 ↗
publication · from DataCite
Catalogue records · 2
- DataCite API api.datacite.org/dois/10.6084/m9.figshare.c.3264160 ↗
metadata API · from DataCite
- DataCite Commons commons.datacite.org/doi.org/10.6084/m9.figshare.c.3264160 ↗
catalogue entry · from DataCite
Topics
- Stated by source
- Chemical sciences · Physical sciences
- From keywords
- Medicine & Health
Related
Provenance · 1 source records, 10 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| DataCite | 10.6084/m9.figshare.c.3264160 | 11 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| access_level | source · DataCite | connector:datacite@1.0.0 | /data/attributes/rightsList |
| concepts[field].fos:chemical-sciences | source · DataCite | connector:datacite@1.0.0 | |
| concepts[field].fos:physical-sciences | source · DataCite | connector:datacite@1.0.0 | |
| concepts[field].local:field:medicine-health | mapping · DataCite | vocabulary-mapper@1.0.0 | keywords['Medicine'] |
| created_date | source · DataCite | connector:datacite@1.0.0 | |
| description | source · DataCite | connector:datacite@1.0.0 | /data/attributes/descriptions |
| license | source · DataCite | connector:datacite@1.0.0 | /data/attributes/rightsList |
| publication_date | source · DataCite | connector:datacite@1.0.0 | /data/attributes/dates |
| title | source · DataCite | connector:datacite@1.0.0 | /data/attributes/titles/0/title |
| updated_date | source · DataCite | connector:datacite@1.0.0 |