Carbonate cement mineralogy, isotope composition, and pore water environment in sediments of ODP Leg 112

Global sea-level fluctuations are the ultimate cause for these cyclic facies changes. During late Miocene time, coastal upwelling was about 100 km west of the present centers, along the edge of an emergent structure that subsequently subsided to form the modern slope.

The sediments are rich in organic carbon, and intense microbially mediated decomposition of organic matter is evident in sulfate reduction and methanogenesis. These processes are accompanied by the formation of diagenetic carbonates, mostly Ca-rich dolomites and Mg-calcites. The downhole isotopic signatures of these carbonate cements display distinct successions that reflect the vertical evolution of the pore fluid environment.