Data · dataset · 2026
ICARUS Chamber Experiment: Caltech Atmospheric Chamber_20130415_trans-beta IEPOX/hydrogen peroxide_Hydroxyl radical_Ammonium sulfate_AqueousPhotooxidation
Listed in National Center for Atmospheric Research
Goals: This is similar to the 130410 experiment except that H2O2 is atomized with ammonium sulfate in the particles.
Description
IEPOX was introduced to hydrated ammonium sulfate at 50% RH, the chamber was cooled to to remove the IEPOX from the gas phase (no more traces in CIMS); this increased the RH to ~80%) then lights turned on to photolyze the IEPOX on the particles.
Summary
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Gaseous H2O2 was not observed when the H2O2 was atomized with AS in the particle, which suggests all the reaction was in the particle phase. The organic aerosol as seen on AMS reacted nearly all away. Fragmentation products such as hydroxyacetone, glycolaldehyde, formic acid, acetic acid, and peroxyacetic acid were seen as products on CIMS Organization: Caltech Atmospheric Chamber Lab Affiliation: California Institute of Technology, Pasadena, CA Chamber: Near/Far Bag 2012-2015 (Tran) Experiment Category: Condensed-phase chemical reaction, Multiphase chemical reaction Oxidant: Hydroxyl radical Reactants: trans-beta IEPOX, hydrogen peroxide Reaction Type: Photooxidation, Heterogeneous oxidation, Other aqueous/aerosol phase Relative Humidity: 49-80 Temperature: 16-22 Seed Name: Ammonium sulfate Pressure: 750 Torr
Links
Get the data
- Resource Homepage doi.org/10.5065/wzcd-nr42 ↗
download · DOI / persistent id · from data ucar edu
Where it is published
- data.ucar.edu /dataset/icarus-chamber-experiment-caltech-atmospheric-chamber_… ↗
National Center for Atmospheric Research dataset page
landing page · from data ucar edu
Catalogue records · 1
- CKAN API data.ucar.edu/api/3/action/package_show?id=e19f0e08-f427-410f-9bae-2d296f4f3… ↗
metadata API · from data ucar edu
Topics
- From keywords
- Chemistry · Earth & Environmental Science · Life Sciences · Ocean & Atmospheric Science · Social Science
Provenance · 1 source records, 10 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| National Center for Atmospheric Research | e19f0e08-f427-410f-9bae-2d296f4f34e9 | 12 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| concepts[field].local:field:chemistry | mapping · data ucar edu | connector:data_ucar_edu@1.0.0 | |
| concepts[field].local:field:earth-environmental | mapping · data ucar edu | connector:data_ucar_edu@1.0.0 | |
| concepts[field].local:field:life-sciences | mapping · data ucar edu | connector:data_ucar_edu@1.0.0 | |
| concepts[field].local:field:ocean-atmospheric | mapping · data ucar edu | connector:data_ucar_edu@1.0.0 | |
| concepts[field].local:field:social-science | mapping · data ucar edu | connector:data_ucar_edu@1.0.0 | |
| created_date | source · data ucar edu | connector:data_ucar_edu@1.0.0 | |
| description | source · data ucar edu | connector:data_ucar_edu@1.0.0 | /notes |
| publication_date | source · data ucar edu | connector:data_ucar_edu@1.0.0 | |
| title | source · data ucar edu | connector:data_ucar_edu@1.0.0 | /title |
| updated_date | source · data ucar edu | connector:data_ucar_edu@1.0.0 |