Table · dataset · 2022
Data for Oxidation of 5‐hydroxymethyl furfural to 2,5‐furan dicarboxylic acid under mild aqueous conditions catalysed by MIL‐100(Fe) metal‐organic framework
Listed in figshare
We present the use of the redox active MIL-100(Fe) metal-organic framework (MOF) as a catalyst for the oxidation of 5-hydroxymethyl furfural (HMF) into 2,5-furan dicarboxylic acid (FDCA) in water.
Description
The MOF is synthesised in water alone under mild hydrothermal conditions and 1H NMR is used to analyse the products of HMF oxidation. The MOF in combination with the co-catalyst TEMPO provides a total selectivity of desired products of 74% with a maximum FDCA yield of 57% seen after 24 hours at only 70 °C. The catalyst is recycled five times with no loss in activity and no evidence of a reduction to the crystallinity of the MOF.<br><br>All data are ascii format and are labelled according to the figures in the paper.
Figure 1B: Powder XRD data. Two-columns: diffraction angle (two-theta) and intensity. Figure S2: TGA data.
Read the rest (2 more)
Two-columns: temperature (degrees Celsius) and % mass. Figure S8: Powder XRD data. Two-columns: diffraction angle (two-theta) and intensity.
Figure S11: Nitrogen adsorption data. Two columns: energy and normalised absorption.
Links
Where it is published
- DOI doi.org/10.82444/warw.33935155.v1 ↗
DOI / persistent id · from figshare com
Catalogue records · 1
- OAI-PMH record api.figshare.com/v2/oai?verb=GetRecord&metadataPrefix=oai_dc&identifier=oai%3Af… ↗
metadata API · from figshare com
Topics
Provenance · 1 source records, 17 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| figshare | oai:figshare.com:article/33935155 | 4 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| access_level | source · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].anzsrc:field:340207 | mapping · figshare com | vocabulary-mapper@1.0.0 | keywords['Metal-organic frameworks'] |
| concepts[field].local:field:astronomy | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:chemistry | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:computer-science-ai | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:earth-environmental | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:economics-finance | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:engineering | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:humanities | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:life-sciences | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:medicine-health | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:ocean-atmospheric | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:social-science | mapping · figshare com | connector:figshare_com@1.0.0 | |
| description | source · figshare com | connector:figshare_com@1.0.0 | /metadata/dc/description |
| license | source · figshare com | connector:figshare_com@1.0.0 | /metadata/dc/rights |
| publication_date | source · figshare com | connector:figshare_com@1.0.0 | |
| title | source · figshare com | connector:figshare_com@1.0.0 | /metadata/dc/title |