Data · collection · 2015
Synthesis of homochiral helical metal–organic frameworks based on lactate derivatives
Listed in DataCite
A pair of homochiral metal–organic frameworks (HMOFs) based on semi-rigid 5-(1-carboxyethoxy)isophthalic acid (H 3 CIA), [Zn 5 (( R )-CIA) 3 (OH) 2 (H 2 O) 4 ]·NH 2 (CH 3 ) 2 ·4.5H 2 O ( 1-D ) and [Zn 5 (( S )-CIA) 3 (OH) 2 (H 2 O) 4 ]·NH 2 (CH 3 ) 2 ·4.5H 2 O ( 1-L ), were synthesized and structurally characterized.
Description
They are enantiomers and exhibit three-dimensional framework structures. In each structure, the CIA ligands link the Zn centers into a homochiral open framework with tetranuclear and trinuclear Zn-clusters.
An interesting double helix built from the connectivity between CIA ligands and Zn centers is presented. The chiral nature of 1-D and 1-L was further confirmed by CD spectra. Photoluminescence of 1-D was also investigated in the solid state at room temperature.
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Where it is published
- Repository landing page tandf.figshare.com/collections/Synthesis_of_homochiral_helical_metal_organic_fram… ↗
landing page · from DataCite
- DOI doi.org/10.6084/m9.figshare.c.2134259.v1 ↗
DOI / persistent id · from DataCite
Documentation and papers
Catalogue records · 2
- DataCite API api.datacite.org/dois/10.6084/m9.figshare.c.2134259.v1 ↗
metadata API · from DataCite
- DataCite Commons commons.datacite.org/doi.org/10.6084/m9.figshare.c.2134259.v1 ↗
catalogue entry · from DataCite
Topics
- Stated by source
- Biological sciences · Clinical medicine · Sociology
- From keywords
- Chemistry · Life Sciences · Medicine & Health · Social Science
Related
Provenance · 1 source records, 14 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| DataCite | 10.6084/m9.figshare.c.2134259.v1 | 15 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
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| concepts[field].fos:biological-sciences | source · DataCite | connector:datacite@1.0.0 | |
| concepts[field].fos:clinical-medicine | source · DataCite | connector:datacite@1.0.0 | |
| concepts[field].fos:sociology | source · DataCite | connector:datacite@1.0.0 | |
| concepts[field].local:field:chemistry | mapping · DataCite | vocabulary-mapper@1.0.0 | keywords['Chemistry'] |
| concepts[field].local:field:life-sciences | mapping · DataCite | vocabulary-mapper@1.0.0 | keywords['Biological Sciences'] |
| concepts[field].local:field:medicine-health | mapping · DataCite | vocabulary-mapper@1.0.0 | keywords['Medicine'] |
| concepts[field].local:field:social-science | mapping · DataCite | vocabulary-mapper@1.0.0 | keywords['Sociology'] |
| created_date | source · DataCite | connector:datacite@1.0.0 | |
| description | source · DataCite | connector:datacite@1.0.0 | /data/attributes/descriptions |
| license | source · DataCite | connector:datacite@1.0.0 | /data/attributes/rightsList |
| publication_date | source · DataCite | connector:datacite@1.0.0 | /data/attributes/dates |
| title | source · DataCite | connector:datacite@1.0.0 | /data/attributes/titles/0/title |
| updated_date | source · DataCite | connector:datacite@1.0.0 |