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Data · dataset · 2025

Characterization of giant porous cages; porous-meltable and janus-type metal organic polyhedra

Listed in TU Wien Research Data

Raw Data for three Publications entitled: 1. "Porous and Meltable Metal–Organic Polyhedra for the Generation and Shaping of Porous Mixed-Matrix Composites" This paper was published on 2024-03-11 in Journal of the American Chemical Society J. Am.

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Chem. Soc. 2024, 146, 11, 7159–7164 DOI: 10.1021/jacs.4c00407 Authors: Cornelia von Baeckmann, Jordi Martínez-Esaín, José A. Suárez del Pino, Lingxin Meng, Joan Garcia-Masferrer, Jordi Faraudo, Jordi Sort, Arnau Carné-Sánchez , Daniel Maspoch Funded by: Austrian Sciene Fund (FWF, project number J4637) ; Spanish MINECO (project RTI2018-095622-B-I00), the Catalan AGAUR (projects 2021 SGR 00458 and 2021 SGR 00651), the CERCA Program/Generalitat de Catalunya, the MCIN/AEI/10.13039/501100011033, and by the European Union “NextGenerationEU”/PRTR (EUR2020-112294); ICN2 is supported by the Severo Ochoa program from the Spanish MINECO (grant SEV-2017-0706).

The project that gave rise to these results received the support of a fellowship (LCF/BQ/PR20/11770011) from “la Caixa” Foundation (ID 100010434). A.C.S. is indebted to the Ramón y Cajal Program (RYC2020-029749-I Fellowship) and the Europa Excelencia grant (EUR2021-121997). J.F. acknowledges the financial support from MCIN/AEI/10.13039/501100011033 agency through Grant PID2021-124297NB-C33 and the “Severo Ochoa” Programme for Centres of Excellence in R&D (CEX2019-000917-S) awarded to ICMAB.

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We also thank the Government of Catalonia (AGAUR) for Grant 2021SGR01519. L.M. acknowledges the China Scholarship Council for scholarship support. 2. " Stepwise assembly of heterometallic, heteroleptic “triblock Janus-type” metal–organic polyhedra" This paper was published on 2023-02-13 in Chem. Commun.

Chem. Commun., 2023, 59, 3423-3426 DOI: 10.1039/D2CC06815J Authors: Cornelia von Baeckmann, Sara Ruiz-Relaño, Inhar Imaz, Marcel Handke, Judith Juanhuix , Felipe Gándara , Arnau Carné-Sanchez and Daniel Maspoch Funded by: Austrian Sciene Fund (FWF, project number J4637); Spanish MINECO (project RTI2018-095622-B-I00), the Catalan AGAUR (project 2021 SGR 00458), the CERCA Program/Generalitat de Catalunya, and the MCIN/AEI/10.13039/501100011033.

ICN2 is supported by the Severo Ochoa program from the Spanish MINECO (grant SEV-2017-0706). The project that gave rise to these results received the support of a fellowship (LCF/BQ/PR20/11770011) from “la Caixa” Foundation (ID 100010434). 3. "Giant oligomeric porous cage-based molecules" This paper was published on 2024-04-30 in Chemical Science Chem. Sci., 2024, 15, 7992-7998 DOI: 10.1039/D4SC01974A Authors: Alba Cortés-Martínez, Cornelia von Baeckmann, Laura Hernández-López, Arnau Carné-Sánchez and Daniel Maspoch Funded by: Austrian Sciene Fund (FWF, project number J4637); Europa Excelencia grant (EUR2021-121997) and the Catalan AGAUR (project 2017 SGR 238).

It was also funded by the CERCA Programme/Generalitat de Catalunya. ICN2 is supported by the Severo Ochoa Centres of Excellence programme, Grant CEX2021-001214-S, funded by MCIN/AEI/10.13039.501100011033. A. C. S. is indebted to the Ramón y Cajal Program (RYC2020-029749-I Fellowship) Context and methodology In these three Publications the synthesis of giant porous cages; porous-meltable and Janus-type metal organic polyhedra are described.

The publications and the corresponding supporting informations can be found as open-access files on the publisher´s websites (see DOI above). Raw data files covering 1H and 13C NMR spectra, gas-adsorption measurments and SEM images for compounds described in these publications are uploaded. Technical details The Zip Files contains raw data obtained from nuclear magnetic resonance measurements; scanning electron microscopy images and gas adsorption measurments.

Specific software required for NMR data = Bruker TopSpin or MestreNova and for gas adsorption = Micromeritics In case of questions; do not hesitate to contact the PI of this Project; Dr. Cornelia von Baeckmann (cornelia.baeckmann@tuwien.ac.at)

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