Carbon and nitrogen rate coefficients

We calculate and study excitation and charge transfer of CI and of NI due to such collisions. We use a previously presented method that is based on an asymptotic two-electron linear combination of atomic orbitals (LCAO) model of ionic-covalent interactions for the adiabatic potential energies, combined with the multichannel Landau- Zener model for the collision dynamics.

We find that charge transfer processes typically lead to much larger rate coefficients than excitation processes, consistent with studies of other atomic species. Two-electron processes were considered and lead to non-zero rate coefficients that can potentially impact statistical equilibrium calculations. However, they were included in the model in an approximate way, via an estimate for the two-electron coupling that was presented earlier in the literature: the validity of these data should be checked in a future work.