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Data · dataset · 2019

XPS data from Structure and catalytic behaviour of CuO–CeO 2 prepared by high-energy ball milling

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The aim of this study is to prepare CeO 2 –CuO composite by means of mechanical milling and to investigate its characteristics as catalyst.

Description

The structural and morphological features of milled samples are observed by X-ray diffractometry and scanning electron microscopy. The milled sample is subjected to measurement of the redox property and total OSC (oxygen storage capacity) using GC-TCD and TG-DTA, which are important parameters to indicate the effectiveness of catalysts.

Interestingly, reduction of CuO is repeatedly observed when milling of CuO–CeO 2 powder mixture is processed in air. The redox property of milled CuO–CeO 2 sample is investigated by H 2 -TPR, where three reduction peaks are observed for 0 h milling and only one broad peak for various other milling times. The total OSC of mechanically driven CuO–CeO 2 catalyst is much higher than that of the CeO 2 –ZrO 2 traditional catalyst system at low temperatures.

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Microscopy 75%

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Provenance · 1 source records, 11 field assertions
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DataCite10.6084/m9.figshare.761960013 d agoJSON v1
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concepts[modality].local:modality:microscopyenrichment · DataCitekeyword-concept-rules@1.0.0title+description (75%)
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