Table · dataset · 2026
Data for High-throughput kinetic screening of UV and visible light-induced copper-RDRP in continuous flow using inline benchtop NMR analysis
Listed in figshare
Photo-induced copper-mediated reversible deactivation radical polymerization (photo-induced Cu-RDRP) is investigated through a simple automated continuous flow platform enabling rapid kinetic screening via inline NMR measurements.
Description
The effect of different molecular weight targets, monomers with various side chain functionalities, changes in solvent and ability to form polymer blocks were monitored in real-time. Offline samples were extracted to confirm the validity of the inline analysis (±4%) as well as size-exclusion chromatography (SEC) to show well-controlled polyacrylates (1.09 ≤ Đ ≤ 1.28) with good end-group fidelity as demonstrated by matrix-assisted laser desorption/ionization time-of-flight (MALDI-ToF).
Low energy visible light could be applied to polymerize polyacrylates using catalytic amounts of appropriate commercially available dyes giving full monomer conversion in only 20 minutes, signifying the efficiency of a user-friendly platform to optimize and monitor polymer synthesis under mild conditions
Links
Where it is published
- DOI doi.org/10.82444/warw.33911269.v1 ↗
DOI / persistent id · from figshare com
Catalogue records · 1
- OAI-PMH record api.figshare.com/v2/oai?verb=GetRecord&metadataPrefix=oai_dc&identifier=oai%3Af… ↗
metadata API · from figshare com
Topics
- From keywords
- Astronomy & Astrophysics · Chemistry · Computer Science & AI · Earth & Environmental Science · Economics & Finance · Engineering · Humanities · Life Sciences · Medicine & Health · Ocean & Atmospheric Science · Social Science
- Inferred from text
- Polymerisation mechanisms 76%
Provenance · 1 source records, 17 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| figshare | oai:figshare.com:article/33911269 | 12 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| access_level | source · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].anzsrc:field:340306 | enrichment · figshare com | taxonomy-embedding@1.0.0 | title+keywords+description (76%) |
| concepts[field].local:field:astronomy | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:chemistry | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:computer-science-ai | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:earth-environmental | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:economics-finance | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:engineering | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:humanities | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:life-sciences | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:medicine-health | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:ocean-atmospheric | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:social-science | mapping · figshare com | connector:figshare_com@1.0.0 | |
| description | source · figshare com | connector:figshare_com@1.0.0 | /metadata/dc/description |
| license | source · figshare com | connector:figshare_com@1.0.0 | /metadata/dc/rights |
| publication_date | source · figshare com | connector:figshare_com@1.0.0 | |
| title | source · figshare com | connector:figshare_com@1.0.0 | /metadata/dc/title |