PKS1830-211 HDO, ND and NH_2_D spectra

Compared to the first component, this second component has XD/XH abundances that are 100 times larger than the primordial D/H ratio, a deepening of the absorption by a factor of two within a few months, and a rich chemical composition, with relative enhancements of N_2_H^+^, CH_3_OH, SO_2_ and complex organic molecules. We therefore speculate that this component is associated with the analog of a Galactic dark cloud, while the first component is likely more diffuse.

Our search for the ^7^LiH (1-0) line was unsuccessful and we derive an upper limit ^7^LiH/H_2_=4x10^-13^ (3{sigma}) in the z=0.89 absorber toward PKS 1830.211. Besides, with ALMA archival data, we could not confirm the previous tentative detections of this line in the z=0.68 absorber toward B0218+357; we derive an upper limit ^7^LiH/H_2_=5x10^-11^ (3{sigma}), although this is less constraining than our limit toward PKS 1830.211.

We conclude that, as in the Milky Way, only a tiny fraction of lithium nuclei are possibly bound in LiH in these absorbers at intermediate redshift.