Archive · collection · 2007
Polyfluorinated alkyl substances (PFAS) in high-volume air samples collected during Polarstern expedition ANT-XXIII/1
Listed in PANGAEA and DataCite — shown once because both records carry DOI 10.1594/pangaea.610160
Neutral, volatile polyfluorinated alkyl substances (PFAS) were determined in high-volume air samples collected onboard the German research vessel Polarstern during cruise ANT-XXIII/1 between Bremerhaven, Germany (53° N) and Capetown, Republic of South Africa (33° S) in fall 2005.
Description
An optimized and validated analytical protocol was used for the determination of several fluorotelomer alcohols (FTOHs) as well as N-alkylated fluorooctane sulfonamides and sulfonamidoethanols (FOSAs/FOSEs).
Quantitative analyses were done by gas chromatography-mass spectrometry. This study provides the first concentration data of airborne PFAS from the Southern Hemisphere. Results indicate a strongly decreasing concentration gradient from the European continent toward less industrialized regions.
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The study confirms that airborne PFAS are mainly restricted to the Northern Hemisphere with a maximum concentration of 190 pg/m**3 (8:2 FTOH) in the first sample collected in the channel between the European mainland and the UK. However, south of the equator, trace amounts of several FTOHs and FOSAs with a maximum of 14 pg/m**3 (8:2 FTOH) could still be detected. Furthermore, a selection of ionic PFAS including perfluorooctane sulfonate (PFOS) and perfluorooctanoate (PFOA) were determined in the particulate phase of high-volume air samples by liquid chromatography-mass spectrometry.
Levels of ionic PFAS were almost 2 orders of magnitude lower than those of neutral PFAS, with maximum concentrations in the first sample of 2.5 pg/m**3 (PFOS) and 2.0 pg/m**3 (PFOA).
Links
Where it is published
- Repository landing page doi.pangaea.de/10.1594/PANGAEA.610160 ↗
landing page · from DataCite
- DOI doi.org/10.1594/pangaea.610160 ↗
DOI / persistent id · from PANGAEA
Documentation and papers
- Creative Commons Attribution 3.0 Unported creativecommons.org/licenses/by/3.0/legalcode ↗
license · from DataCite
- IsSupplementTo 10.1021/es062389h doi.org/10.1021/es062389h ↗
publication · from DataCite
Catalogue records · 3
- OAI-PMH record ws.pangaea.de/oai/provider?verb=GetRecord&metadataPrefix=oai_dc&identifier=o… ↗
metadata API · from PANGAEA
- DataCite API api.datacite.org/dois/10.1594/pangaea.610160 ↗
metadata API · from DataCite
- DataCite Commons commons.datacite.org/doi.org/10.1594/pangaea.610160 ↗
catalogue entry · from DataCite
Topics
- From keywords
- Earth & Environmental Science
Provenance · 2 source records, 7 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| PANGAEA | oai:pangaea.de:doi:10.1594/PANGAEA.610160 | 11 d ago | JSON v1 |
| DataCite | 10.1594/pangaea.610160 | 11 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| access_level | source · PANGAEA | connector:pangaea@1.0.0 | |
| concepts[field].local:field:earth-environmental | mapping · PANGAEA | connector:pangaea@1.0.0 | |
| description | source · PANGAEA | connector:pangaea@1.0.0 | /metadata/dc/description |
| license | source · PANGAEA | connector:pangaea@1.0.0 | /metadata/dc/rights |
| publication_date | source · PANGAEA | connector:pangaea@1.0.0 | |
| spatial | source · PANGAEA | connector:pangaea@1.0.0 | |
| title | source · PANGAEA | connector:pangaea@1.0.0 | /metadata/dc/title |