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Data · dataset · 2021

Replication data of Buchmeiser group for: "Tungsten Sulfido Alkylidene and Cationic Tungsten Sulfido Alkylidene N-Heterocyclic Carbene Complexes"

Listed in DaRUS

The synthesis of neutral tungsten sulfido alkylidene complexes as well as cationic tungsten alkylidene NHC complexes is outlined.

Description

The first tungsten sulfido alkylidene complexes for olefin metathesis reactions were synthesized. Alkylidyne complexes were used as precursors and were reacted with hydrogen sulfide to protonate the alkylidyne ligand.

Data from collaborating groups can be found in a separate data set. The data is structured according to figures and schemes in the research article and contains the following data types: NMR Spectra and integrals of GC-MS measurements. GC-MS data was evaluated with MassHunter software by agilent.

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NMR data was evaluated with MestreNova. Crystal data (see related datasets) is deposited in the Cambridge Structural Database (CSD) of the Cambridge Crystallographic Data Centre (CCDC).

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Where it is published

Catalogue records · 1

Topics

Stated by source
Chemistry
From keywords
Chemistry
Provenance · 1 source records, 8 field assertions
SourceKeyLast seenRaw
DaRUSdoi:10.18419/DARUS-229713 d agoJSON v1
FieldAssertionExtractorEvidence
concepts[field].dataverse_subject:chemistrysource · darus uni stuttgart deconnector:darus_uni_stuttgart_de@1.0.0/subjects
concepts[field].local:field:chemistrymapping · darus uni stuttgart deconnector:darus_uni_stuttgart_de@1.0.0/subjects
created_datesource · darus uni stuttgart deconnector:darus_uni_stuttgart_de@1.0.0
descriptionsource · darus uni stuttgart deconnector:darus_uni_stuttgart_de@1.0.0/description
publication_datesource · darus uni stuttgart deconnector:darus_uni_stuttgart_de@1.0.0
titlesource · darus uni stuttgart deconnector:darus_uni_stuttgart_de@1.0.0/name
updated_datesource · darus uni stuttgart deconnector:darus_uni_stuttgart_de@1.0.0
version_labelsource · darus uni stuttgart deconnector:darus_uni_stuttgart_de@1.0.0