Data · dataset · 2026
ICARUS Chamber Experiment: Caltech Atmospheric Chamber_20140816_2-Methyl-3-buten-1-ol/Methyl nitrite/10102-44-0/OZONE_Hydroxyl radical_No Seed_Dry
Listed in National Center for Atmospheric Research
Goals: This experiment was done to react 2-Methyl-3-buten-1-ol (231 MBO) with ozone to produce the Hydroxymethylpropanal (HMPR).
Description
After oxidizing HMPR with OH in the high NO2 condition, we get the HMPR-PAN (or the peroxynitrate of HMPR). This is analogous to MPAN except it has an OH at the 1-position and no double bond, so that when OH abstracts a hydrogen from HMPR-PAN, it makes the exact same alkyl radical as OH addition to MPAN.
The only difference is that the alkyl radical from OH + HMPR-PAN is not created with excess energy, compared to OH addition radicals. Thus... the thermalized radical from HMPR-PAN is not hypothesized to have enough energy to form HMML, and therefore won't form secondary organic aerosol (SOA).
Read the rest (3 more)
Summary
The reaction did not produce any significant amounts of SOA from the OH+HMPR-PAN reaction. Therefore the hypothesis is validated, that the alkyl radical of MPAN +OH goes to HMML because it is formed with excess energy through OH addition. We showed the exact same alkyl radical with less energy will add O2 instead of decomposing to HMML.
Organization: Caltech Atmospheric Chamber Lab Affiliation: California Institute of Technology, Pasadena, CA Chamber: Near/Far Bag 2012-2015 (Tran) Experiment Category: Gas phase chemical reaction, Aerosol formation Oxidant: Hydroxyl radical Reactants: 2-Methyl-3-buten-1-ol, Methyl nitrite, 10102-44-0, OZONE Reaction Type: Photooxidation Relative Humidity: 4 Temperature: 25 Pressure: 750 Torr
Links
Get the data
- Resource Homepage doi.org/10.5065/cfwy-wk15 ↗
download · DOI / persistent id · from data ucar edu
Where it is published
- data.ucar.edu /dataset/icarus-chamber-experiment-caltech-atmospheric-chamber_… ↗
National Center for Atmospheric Research dataset page
landing page · from data ucar edu
Catalogue records · 1
- CKAN API data.ucar.edu/api/3/action/package_show?id=8099ef53-8538-44cd-8d2f-26c9c866c… ↗
metadata API · from data ucar edu
Topics
- From keywords
- Chemistry · Earth & Environmental Science · Life Sciences · Ocean & Atmospheric Science · Social Science
Provenance · 1 source records, 10 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| National Center for Atmospheric Research | 8099ef53-8538-44cd-8d2f-26c9c866c6fa | 9 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| concepts[field].local:field:chemistry | mapping · data ucar edu | connector:data_ucar_edu@1.0.0 | |
| concepts[field].local:field:earth-environmental | mapping · data ucar edu | connector:data_ucar_edu@1.0.0 | |
| concepts[field].local:field:life-sciences | mapping · data ucar edu | connector:data_ucar_edu@1.0.0 | |
| concepts[field].local:field:ocean-atmospheric | mapping · data ucar edu | connector:data_ucar_edu@1.0.0 | |
| concepts[field].local:field:social-science | mapping · data ucar edu | connector:data_ucar_edu@1.0.0 | |
| created_date | source · data ucar edu | connector:data_ucar_edu@1.0.0 | |
| description | source · data ucar edu | connector:data_ucar_edu@1.0.0 | /notes |
| publication_date | source · data ucar edu | connector:data_ucar_edu@1.0.0 | |
| title | source · data ucar edu | connector:data_ucar_edu@1.0.0 | /title |
| updated_date | source · data ucar edu | connector:data_ucar_edu@1.0.0 |