ExoMol line lists. Spectra of SH and NS

These line lists consider transitions within the ground electronic state for isotopologues of SH and NS. Ab initio potential energy (PEC), and spin-orbit coupling (SOC) curves are computed and then improved by fitting to experimentally observed transitions.

Fully ab initio dipole moment curves (DMCs) computed at the high level of theory are used to produce the final line list. For SH, our fit gives a root-mean-square (rms) error of 0.03cm^-1^ between the observed (v_max_=4, J_max_=34.5) and calculated transitions wavenumbers; this is extrapolated such that all possible X bound states are considered. For ^32^SH the resulting line list contains about 81,000 transitions and 2300 rovibronic states, considering levels up to vmax=14 and Jmax=60.5.