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Data · dataset · 2016

Synthesis, Crystal Structure, and Properties of a New Zinc(II) Coordination Polymer With Mixed 4,4′-biphenyldisulfonic Acid and N-Donor Ligands

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A new zinc(II) coordination polymer, namely [Zn(bipy) 2 (H 2 O) 4 ] n · n (dsba) (1), has been synthesized by the mixed 4,4′-biphenyldisulfonic acid (H 2 dsba) and 4,4′-bipyridine (bipy) ligands with Zinc(II) salt under the common solution evaporation method.

Description

The results of the X-ray crystal diffraction analysis show that complex 1 belongs to the monoclinic system with P2 1 /c space group. The unit cell constants of complex 1 are a = 9.2579 Å, b = 12.2016 Å, c = 14.447 Å, α = γ = 90˚, β = 93.476˚.

Complex 1 exhibits a three-dimensional supramolecular network based on the discrete structure by utilizing various H-bonded interactions. In addition, the properties of complex 1, such as the elemental analysis, FT-IR spectroscopy, X-ray powder diffraction, and fluorescence spectroscopy were also characterized and are discussed in detailed.

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Medicine & Health

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DataCite10.6084/m9.figshare.3503480.v110 d agoJSON v1
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concepts[field].local:field:medicine-healthmapping · DataCitevocabulary-mapper@1.0.0keywords['Medicine']
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